Methyl iodide similarly proved unreactive as a function of humidity and temperature. Different types of alcohols may dehydrate through a slightly different mechanism pathway. Use alcohol resistant foam or flood with fine water spray. Details of manufacturer or importer manufacturer glaxosmithkline australia phamaceuticals and vaccines 1061 mountain highway melbourne, victoria 3155 australia general information phone number normal business hours.
Msds 3,3dimethyl2butanol, 99% cas 464073 msds tert. Material safety data sheet msds isopropyl alcohol product identification product name. Safety data sheet 1,1,2,2tetraphenylethane1,2diol page. June 1, 2001 aaper alcohol and chemical company 1101 isaac shelby drive, p. For large fires, apply water from as far as possible. For small incipient fires, use media such as alcohol foam, dry chemical, or carbon dioxide. Sigmaaldrich material safety data sheet product name. Alkenes from dehydration of alcohols chemistry libretexts. I suspect this is a set question, but if you are remotly interested in doing this i suggest you use the magnesiummagnesium iodide method to make the pinacol rather than the magnesium amalgam method. Material safety data sheet methyl acetate section 1 chemical product and company identification msds name.
Pinacolyl alcohol appears on the list of schedule 2 substances cwc as. Recommended use restrictions on use no other uses are advised. Exposure controls personal protection control parameters, e. Ga has a slightly fruity odor, and gd has a slight camphorlike odor. It is a colourless liquid that is slightly soluble in water 2 ml100 ml h 2 o, but miscible with most organic solvents. Occupational exposure limits component source type value note ethyl alcohol us acgih stel ppm. Pinacolyl alcohol chemical information, properties, structures, articles, patents and more chemical data. Pinacolyl alcohol appears on the list of schedule 2 substances cwc as a precursor for the nerve agent soman. Empty containers pose a fire risk, evaporate the residue under a fume hood. One reagent lane fair lawn, nj 07410 for information in north america, call.
Growth inhibition tests 96 hr were conducted using ankistrodesmus falcatus, ec50 257. Mechanism for the dehydration of alcohol into alkene. Click on any of the following chemicals below to download the msds sheet. Azer scientific inc 701 hemlock road morgantown pa 19543 610. Pinacolone 3,3dimethyl2butanone is an important ketone in organic chemistry. Composition information ingredient cas no proportion ethanol 64175 70% vv macadamia oil 12849201 msds and with local authorities.
Composition information ingredient cas no proportion ethanol 64175 70% vv macadamia oil 12849201 alcohol gel issue no. Discontinue use if skin irritation and redness develop. In rats it is suggested that pinacolyl alcohol is metabolised by alcohol dehydrogenase with the major metabolite being pinacolone james et al, 1987. Alcohols can now be analyzed by a direct analysis in real. No warranty, express or implied, is made and qorpak assumes no liability resulting from the use of this msds.
In such cases chromatography was unnecessary, and simple removal of the solvent after filtration provided the nearpure boronic acid with only a trace of. The gtype agents are clear, colorless, tasteless liquids miscible in water and most organic solvents. In general higher yields were obtained using the acetonitrile1 m hcl method, in many cases giving the boronic acids 2 in 90% yield. When clicked the sheets are downloaded to your harddrive in a.
Boiling point vapor density air1 vapor pressure evaporation rate nbuac1 emergency first aid. Cool containers with water spray until well after the fire is out. Msds is from available published sources and is believed to be accurate. To study the oxidation of secondary alcohols to ketones using cyclic microwave heating technique. Move container from fire area if it can be done without risk. He prepared it by the reaction of sodium hypochlorite with picric acid.
Employee must wear splashproof or dustresistant safety goggles to prevent eye contact with this substance emergency wash facilities. Pinacolyl alcohol s molecular formula is c 6 h 14 o and is a secondary alcohol. Safety data sheet molecular weight not applicable chemical name cas number % by weight silica gel 7631869 proprietary cellulose 9004346 proprietary sodium lauryl sulfate 1512 1 composition there are no additional ingredients present which, within the current knowledge of the supplier and in the. Application 3,3dimethyl2butanol pinacolyl alcohol can be used as a substrate. A mixture of benzyl alcohol and 58% sulfuric acid decomposed violently when heated to 180c. The peaks of the chromatogram were conclusive in determining and confirming our hypothesis of the production. Other information msds first issued 28032007 classification and labelling have been performed according to eu directives 67548eec, 88379eec, including amendments and the intended use. Hazards from combustion products toxic andor irritating fumes including carbon monoxide and carbon dioxide may be emitted. Sciencemadness discussion board pinacolyl alcohol and. Material safety data sheet isopropyl alcohol, 50100% vv section 1. Immediate effects can be expected after shortterm exposure. Chloropicrin was discovered in 1848 by scottish chemist john stenhouse. The impact of humidity, temperature and ultraviolet light.
Chloropicrin, also known as ps and nitrochloroform, is a chemical compound currently used as a broadspectrum antimicrobial, fungicide, herbicide, insecticide, and nematicide. Use very large quantities flooding of water applied as a mist or spray. The peaks of the chromatogram were conclusive in determining and confirming our hypothesis of. Its chemical structural formula is cl 3 cno 2 synthesis. This one is more obvious than it looks from the structure.
This ion acts as a very good leaving group which leaves to form a. Remove from source of exposure and get medical attention for any breathing difficulty. Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. Where there is any possibility that an employees eyes and or skin may be exposed to. Aug 23, 2004 various aryl pinacolyl boronate esters 1 were then deprotected using these conditions, as shown in table 2. Safety data sheet according to federal register vol. Use alcoholresistant foam or flood with fine water spray. Acute tests were conducted on pimephales promelas, 48 hr ec50 443. It is a colorless liquid and has a slight peppermint or camphor odor. It occurs widely in nature, being found in a variety of essential oils. Nerve agents ga, gb, gd soman, and vx are manufactured compounds. The user must determine suitability of this information for his application.
Material safety data sheet isopropyl alcohol coleparmer. Sbccom online site search data lewisite poiso date. Indication of any immediate medical attention and special treatment needed. Army soldier and biological chemical command sbccom. Analysis of the mechanism of asymmetric amplification by chiral auxiliary trans1,2diaminocyclohexane bistriflamide. Our team of scientists has experience in all areas of research including life science, material science, chemical synthesis, chromatography, analytical and many others. Various aryl pinacolyl boronate esters 1 were then deprotected using these conditions, as shown in table 2. It is a precursor to triazolylpinacolone in the synthesis of the fungicide triadimefon and in synthesis of the herbicide metribuzin.
Pinacolyl alcohol is a common name for 3,3dimethyl2butanol, also known as pine alcohol. Aquatic species the aquatic toxicity of a secondary alcohol, 3,3dimethyl2butanol pinacolyl alcohol pa, was determined. The statements contained herein are based upon technical data that nicepak products, inc. None of the alkyl isocyanates were as suitable as phenyl isocyanate. Firefighting measure suitable extinguishing media use dry chemical, alcohol stable foam, carbon dioxide or fog type extinguishers. These files can be easily viewed in adobe acrobat reader. In such cases chromatography was unnecessary, and simple removal of the solvent after filtration provided.
This page contains pharmcos material safety data sheets. A novel gaseous pinacolyl alcohol sensor utilizing cataluminescence on alumina nanowires prepared by supercritical fluid drying. Phenethyl alcohol, or 2phenylethanol, is the organic compound that consists of a phenethyl group c 6 h 5 ch 2 ch 2 group attached to oh. Structure, properties, spectra, suppliers and links for. Do not induce vomiting if patient is unconscious or extremely drowsy. There may be irritation of the throat with a feeling of tightness in the chest. Section 1 chemical product and company identification.
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